2-D metalloporphyrin coordination network of cobalt-meso-tetra(4-carboxyphenyl)porphyrin

被引：7

作者：

Yan, Bangbo ^{[1
]}

Liu, Xin ^{[1
]}

Ghugare, Tushar ^{[1
]}

Fedorka, Nicholas ^{[1
]}

Li, Yan-Fen ^{[1
]}

机构：

[1] Western Kentucky Univ, Dept Chem, Bowling Green, KY 42101 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 68卷 / 16期

关键词：

Metalloporphyrin; 2-D; Cobalt; Metal-organic framework; Crystal structure; Fluorescence; Hydrogen bond; METAL-ORGANIC FRAMEWORKS; POLYMERS; SERIES; CENTERS; UNITS;

D O I：

10.1080/00958972.2015.1061657

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metalloporphyrin coordination framework [Co(H3TCPP)] (H6TCPP=meso-tetra(4-carboxyphenyl)porphyrin) has been synthesized hydrothermally. Single-crystal X-ray analysis revealed it exhibits a 2-D layered coordination network structure. Hydrogen bonds are observed between carboxyl groups within the 2-D layer as well as from adjacent layers. The UV-Vis diffuse reflectance spectrum indicates the presence of the expected B (410nm) and Q (540 and 690nm) absorption bands. The fluorescence spectrum shows four emission bands centered at 648nm.

引用

页码：2827 / 2834

页数：8

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