2-D metalloporphyrin coordination network of cobalt-meso-tetra(4-carboxyphenyl)porphyrin

被引：7
|
作者：
Yan, Bangbo [1 ]
Liu, Xin [1 ]
Ghugare, Tushar [1 ]
Fedorka, Nicholas [1 ]
Li, Yan-Fen [1 ]
机构：
[1] Western Kentucky Univ, Dept Chem, Bowling Green, KY 42101 USA
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 68卷 / 16期
关键词：
Metalloporphyrin; 2-D; Cobalt; Metal-organic framework; Crystal structure; Fluorescence; Hydrogen bond; METAL-ORGANIC FRAMEWORKS; POLYMERS; SERIES; CENTERS; UNITS;
D O I：
10.1080/00958972.2015.1061657
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new metalloporphyrin coordination framework [Co(H3TCPP)] (H6TCPP=meso-tetra(4-carboxyphenyl)porphyrin) has been synthesized hydrothermally. Single-crystal X-ray analysis revealed it exhibits a 2-D layered coordination network structure. Hydrogen bonds are observed between carboxyl groups within the 2-D layer as well as from adjacent layers. The UV-Vis diffuse reflectance spectrum indicates the presence of the expected B (410nm) and Q (540 and 690nm) absorption bands. The fluorescence spectrum shows four emission bands centered at 648nm.
引用
收藏
页码：2827 / 2834
页数：8
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