A Novel Layer Crystal Structure of Sr(II) Complex based on 2-methyl-1H-imidazole-4,5-dicarboxylate Ligand

被引：0
|
作者：
Zhou, K. [1 ,2 ]
Yue, F. [1 ,2 ]
Chen, H. M. [1 ,2 ]
Liu, T. T. [3 ]
Wang, J. D. [1 ,2 ]
机构：
[1] Xinjiang Univ, Minist Educ, Key Lab Oil & Gas Fine Chem, Urumqi 830046, Peoples R China
[2] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
[3] Xinjiang Shihezi Vocat Tech Coll, Shihezi 832000, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 12期
基金：
中国国家自然科学基金;
关键词：
2-methyl-1H-imidazole-4; 5-dicarboxylate; strontium; coordination polymer; ORGANIC FRAMEWORKS; IMIDAZOLE-4,5-DICARBOXYLATE; STRONTIUM; CALCIUM;
D O I：
10.1134/S1070328419010147
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A layer coordination polymer of [Sr(H2MIDC)(2)(H2O)(2)](n), (H3MIDC = 2-methyl-1H-imidazole-4,5-dicarboxylate) has been synthesized and characterized. Single X-ray structural analysis indicates the title compound crystallizes in a monoclinic lattice, P2(1)/n with a = 6.902(1) b = 14.469(3), c = 16.641(3) angstrom, = 98.58(3)degrees, Z = 4, V = 1643.2(6) angstrom(3), (c) = 1.867 g/cm(3), F(000) = 928, S = 1.079, R-1 = 0.1346, wR(2) = 0.3892 (CIF file CCDC no. 791212). Crystal structure analysis reveals that Sr2+ ion is eight-coordinate and lies in a bicapped tetragonal bipyramid environment with one nitrogen atom and seven oxygen atoms. For the variaties of the ligand's coordination modes and the bridging oxygen atom in carboxylate group, the structure presents a two-dimensional layer molecular network. This coordination polymer exhibited intense fluorescent emissions in the solid state at room temperature.
引用
收藏
页码：800 / 805
页数：6
相关论文
共 50 条
  • [21] Synthesis,structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate
    Li-Zhuang Chen
    Deng-Deng Huang
    Chinese Chemical Letters, 2014, 25 (02) : 279 - 282
  • [22] Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate
    Chen, Li-Zhuang
    Huang, Deng-Deng
    CHINESE CHEMICAL LETTERS, 2014, 25 (02) : 279 - 282
  • [23] A Novel Gd Coordination Polymer Based on 2-(Pyridin-3-yl)-1H-imidazole-4,5-dicarboxylate: Synthesis, Structure and Dielectric Properties
    Huang Deng-Deng
    Chen Li-Zhuang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (03) : 361 - 366
  • [24] Synthesis, Crystal Structure, and Fluorescent Property of a Cd(II) Coordination Polymer Based on 2-Propyl-imidazole-4,5-dicarboxylate and 4,4-Bipyridine
    Deng Ji-Hua
    Zhong Di-Chang
    Mei Guang-Quan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (01) : 175 - 179
  • [25] The first 3D Zn(II) complex involving chiral chains constructed by achiral ligand 2-(hydroxyn-iethyl)-1H-imidazole-4,5-dicarboxylate
    Yang, Huai-Xia
    Jian, Shou-Jun
    Liang, Zhen
    Zhang, Jun-Di
    Meng, Xiang-Ru
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 61 : 57 - 59
  • [26] Three New Supramolecular Complexes Based on 2-Propyl-1H-imidazole-4,5-dicarboxylate: Synthesis, Structures and Properties
    Li, Xiao-Xu
    Yue, Shan-Tang
    Wang, Ning
    Li, Zhao-Yang
    Liu, Ying-Liang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (13-14): : 2481 - 2486
  • [27] Assembly of five metal-organic frameworks based on 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylate
    Cao, Xinjiang
    Liu, Ying
    Wang, Luying
    Li, Gang
    INORGANICA CHIMICA ACTA, 2012, 392 : 16 - 24
  • [28] Synthesis, Structures, and Properties of a Series of New Coordination Polymers Built from 2-Ethyl-1H-imidazole-4,5-dicarboxylate Ligand
    Li, Shijie
    Song, Wendong
    Miao, Dongliang
    Hu, Shiwei
    Ji, Lili
    Ma, Deyun
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (09): : 1246 - 1252
  • [29] The Zn(II)-organic coordination polymers based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate ligands: Crystal structures and luminescent properties
    Zhang, Shu-Quan
    Jiang, Fei-Long
    Wu, Ming-Yan
    Feng, Rui
    Ma, Jie
    Xu, Wen-Tao
    Hong, Mao-Chun
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (09) : 1400 - 1405
  • [30] Syntheses, Crystal Structures, and Properties of Two IB Group Metal Coordination Polymers Based on 2-(Trifluoromethyl)-1H-Imidazole-4,5-Dicarboxylate
    Cai, S. L.
    Lin, H. M.
    Yang, J. R.
    He, Z. Q.
    Fu, S. Q.
    Xu, Z. B.
    Zheng, S. R.
    Zhang, W. G.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2018, 44 (01) : 64 - 71
12345