Rh(III)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C-H activation

被引：97

作者：

Shi, Zhuangzhi ^{[1
]}

Boultadakis-Arapinis, Melissa ^{[1
]}

Koester, Dennis C. ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 20期

基金：

欧洲研究理事会;

关键词：

AROMATIC IMINES; EFFICIENT SYNTHESIS; BOND ACTIVATION; ANNULATION; INDOLIZIDINE; HYDROARYLATION; AGONIST; ALKYNES; ACID;

D O I：

10.1039/c4cc00029c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biologically interesting fused oligocyclic lactams have been prepared via an intramolecular redox-neutral cyclization process. By the proper choice of the substrates with a wide variety of tethered olefins, the less favored C-H bond can be activated and functionalized. This C-H activation proceeds under mild conditions, obviates the need for external oxidants, and displays a broad scope with respect to the substituents.

引用

页码：2650 / 2652

页数：3

共 50 条

[41] Regioselective Synthesis of Indoles via Rhodium-Catalyzed C-H Activation Directed by an In-Situ Generated Redox-Neutral Group
Muralirajan, Krishnamoorthy
Cheng, Chien-Hong
ADVANCED SYNTHESIS & CATALYSIS, 2014, 356 (07) : 1571 - 1576
[42] Ruthenium-Catalyzed Redox-Neutral [4+1] Annulation of Benzamides and Propargyl Alcohols via C-H Bond Activation
Wu, Xiaowei
Wang, Bao
Zhou, Shengbin
Zhou, Yu
Liu, Hong
ACS CATALYSIS, 2017, 7 (04): : 2494 - 2499
[43] Ruthenium(II)-Catalyzed Redox-Neutral C-H Alkylation of Arylamides with Unactivated Olefins
Shambhavi, Chikkabagilu Nagaraju
Jeganmohan, Masilamani
ORGANIC LETTERS, 2021, 23 (12) : 4849 - 4854
[44] Stereoselective β-F Elimination Enabled Redox-Neutral [4+1] Annulation via Rh(III)-Catalyzed C-H Activation: Access to Z-Monofluoroalkenyl Dihydrobenzo[d]isoxazole Framework
Gao, Hui
Sun, Ming
Zhang, Haiman
Bian, Mengyao
Wu, Min
Zhu, Guoxun
Zhou, Zhi
Yi, Wei
ORGANIC LETTERS, 2019, 21 (13) : 5229 - 5233
[45] Regioselective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C-H Alkynylation
Mondal, Shobhan
Pinkert, Tobias
Daniliuc, Constantin G.
Glorius, Frank
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (11) : 5688 - 5692
[46] Rh(III)-Catalyzed C-H Diamidation and Diamidation/Intramolecular Cyclization of N-Iminopyridinium Ylides with Dioxazolones
Li, Xiang
Zhao, Qing
Shen, Yang
Ma, Ran
JOURNAL OF ORGANIC CHEMISTRY, 2022, 87 (05): : 3468 - 3481
[47] Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization
Wang, Hongli
Huang, Hanmin
CHEMICAL RECORD, 2016, 16 (04): : 1807 - 1818
[48] Aerobic Oxidative Alkenylation of Weak O-Coordinating Arylacetamides with Alkenes via a Rh(III)-Catalyzed C-H Activation
Jambu, Subramanian
Sivasakthikumaran, Ramakrishnan
Jeganmohan, Masilamani
ORGANIC LETTERS, 2019, 21 (05) : 1320 - 1324
[49] Redox-Neutral Rh(III)-Catalyzed Olefination of Carboxamides with Trifluoromethyl Allylic Carbonate
Park, Jihye
Han, Sangil
Jeon, Mijin
Mishra, Neeraj Kumar
Lee, Seok-Yong
Lee, Jong Suk
Kwak, Jong Hwan
Um, Sung Hee
Kim, In Su
JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (22): : 11353 - 11359
[50] N-Tosylhydrazone as an oxidizing directing group for the redox-neutral access to isoquinolines via Cp*Co(III)-Catalyzed C-H/N-N activation
Deshmukh, Dewal S.
Gangwar, Neha
Bhanage, Bhalchandra M.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2021, 98 (02)

← 1 2 3 4 5 →