Rh(III)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C-H activation

被引：97

作者：

Shi, Zhuangzhi ^{[1
]}

Boultadakis-Arapinis, Melissa ^{[1
]}

Koester, Dennis C. ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 20期

基金：

欧洲研究理事会;

关键词：

AROMATIC IMINES; EFFICIENT SYNTHESIS; BOND ACTIVATION; ANNULATION; INDOLIZIDINE; HYDROARYLATION; AGONIST; ALKYNES; ACID;

D O I：

10.1039/c4cc00029c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biologically interesting fused oligocyclic lactams have been prepared via an intramolecular redox-neutral cyclization process. By the proper choice of the substrates with a wide variety of tethered olefins, the less favored C-H bond can be activated and functionalized. This C-H activation proceeds under mild conditions, obviates the need for external oxidants, and displays a broad scope with respect to the substituents.

引用

页码：2650 / 2652

页数：3

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