Dielectric spectroscopy of polypyrrole-γ-Fe2O3 composites

被引:13
|
作者
Murugendrappa, M. V.
Prasad, M. V. N. Ambika [1 ]
机构
[1] Gulbarga Univ, Dept Mat Sci & Phys, Gulbarga 585106, Karnataka, India
[2] GM Inst Technol, Dept Phys, Davangere 577006, Karnataka, India
关键词
composites; CONDUCTING POLYMERS; POLYPYRROLE FILMS; CAPACITORS; BIOSENSORS; BATTERY;
D O I
10.1016/j.materresbull.2005.12.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In situ polymerization of pyrrole was carried out in the presence of gamma-Fe2O3 (FE) to synthesize polypyrrole-gamma-Fe2O3 composites (PPy/FE) by chemical oxidation method. The PPy/FE composites have been synthesized with various compositions viz., 10, 20, 30, 40 and 50 wt.% of gamma-Fe2O3 in pyrrole. The AC conductivity was studied in the frequency range 10(2)-10(7) Hz. The dielectric behaviour was also investigated in the frequency range 10(2)-10(7) Hz. The dimensions of gamma-Fe2O3 particles in the matrix have a greater influence on the conductivity values and the observed dielectric values. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1364 / 1369
页数:6
相关论文
共 50 条
  • [31] Thermally induced solid-state syntheses of γ-Fe2O3 nanoparticles and their transformation to α-Fe2O3 via ε-Fe2O3
    Zboril, R
    Mashlan, M
    Barcova, K
    Vujtek, M
    HYPERFINE INTERACTIONS, 2002, 139 (1-4): : 597 - 606
  • [32] Thermally Induced Solid-State Syntheses of γ-Fe2O3 Nanoparticles and Their Transformation to α-Fe2O3 via ε-Fe2O3
    R. Zboril
    M. Mashlan
    K. Barcova
    M. Vujtek
    Hyperfine Interactions, 2002, 139-140 : 597 - 606
  • [33] Nucleation of the electroactive β-phase, dielectric and magnetic response of poly(vinylidene fluoride) composites with Fe2O3 nanoparticles
    Goncalves, R.
    Martins, P. M.
    Caparros, C.
    Martins, P.
    Benelmekki, M.
    Botelho, G.
    Lanceros-Mendez, S.
    Lasheras, A.
    Gutierrez, J.
    Barandiaran, J. M.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2013, 361 : 93 - 99
  • [34] Dielectric and magnetic properties of cobalt doped γ-Fe2O3 nanoparticles
    Hussain, Muhammad
    Khan, Rajwali
    Zulfiqar
    Khan, Tahir Zeb
    Khan, Gulzar
    Khattak, Shaukat
    Rahman, Muneeb Ur
    Ali, Shahid
    Iqbal, Zainab
    Burhanullah
    Safeen, Kashif
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (14) : 13698 - 13707
  • [35] Investigations on dielectric properties of polymer nanocomposites of PANI/Fe2O3
    Basavaraj, Bharati
    Sannakki, Basavaraja
    BULLETIN OF MATERIALS SCIENCE, 2021, 44 (03)
  • [36] Synthesis and Physical Characterization of γ-Fe2O3 and (α plus γ)-Fe2O3 Nanoparticles
    Bhavani, P.
    Reddy, N. Ramamanohar
    Reddy, I. Venkata Subba
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2017, 70 (02) : 150 - 154
  • [37] Crystal Structure of β-Fe2O3 and Topotactic Phase Transformation to α-Fe2O3
    Danno, Teruaki
    Nakatsuka, Daisuke
    Kusano, Yoshihiro
    Asaoka, Hiroshi
    Nakanishi, Makoto
    Fujii, Tatsuo
    Ikeda, Yasunori
    Takada, Jun
    CRYSTAL GROWTH & DESIGN, 2013, 13 (02) : 770 - 774
  • [38] Unusual combination of conduction and dielectric relaxations in nanocrystalline α-Fe2O3
    Pulikkathumbayil, Muhammed Junais
    Govindaraj, G.
    MATERIALS LETTERS, 2020, 264
  • [39] Investigations on dielectric properties of polymer nanocomposites of PANI/Fe2O3
    Bharati Basavaraj
    Basavaraja Sannakki
    Bulletin of Materials Science, 2021, 44
  • [40] Dielectric and magnetic properties of cobalt doped γ-Fe2O3 nanoparticles
    Muhammad Hussain
    Rajwali Khan
    Tahir Zeb Zulfiqar
    Gulzar Khan
    Shaukat Khan
    Muneeb Ur Khattak
    Shahid Rahman
    Zainab Ali
    Kashif Iqbal
    Journal of Materials Science: Materials in Electronics, 2019, 30 : 13698 - 13707