2H and 13C NMR investigation of deuterofullerites C60Dx

被引：7
|
作者：
Tarasov, VP
Muravlev, YB
Fokin, VN
Shulga, YM [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2004年 / 78卷 / 07期
关键词：
D O I：
10.1007/s00339-003-2421-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Deuterofullerites C60Dx have been studied by H-2 and C-13 NMR. These fullerites have two types of carbon-deuterium bonds: C-D terminal bonds, characterized by the quadrupole coupling constant (QCC) of 171 kHz, and -C...D...C-bridging bonds with a QCC of 56 kHz. The latter is responsible for the rigid lattice found in these fullerites, which is untypical of fullerenes.
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收藏
页码：1001 / 1003
页数：3
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