2H and 13C NMR investigation of deuterofullerites C60Dx

被引:7
|
作者
Tarasov, VP
Muravlev, YB
Fokin, VN
Shulga, YM [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, Inst Gen & Inorgan Chem, Moscow 119991, Russia
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关键词
D O I
10.1007/s00339-003-2421-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Deuterofullerites C60Dx have been studied by H-2 and C-13 NMR. These fullerites have two types of carbon-deuterium bonds: C-D terminal bonds, characterized by the quadrupole coupling constant (QCC) of 171 kHz, and -C...D...C-bridging bonds with a QCC of 56 kHz. The latter is responsible for the rigid lattice found in these fullerites, which is untypical of fullerenes.
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页码:1001 / 1003
页数:3
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