A Two-Step Valence Tautomeric Transition in a Dinuclear Cobalt Complex

被引：56
|
作者：
Alley, Kerwyn G. [1 ]
Poneti, Giordano [2 ,3 ,4 ]
Aitken, Jade B. [5 ,6 ,7 ]
Hocking, Rosalie K. [8 ]
Moubaraki, Boujemaa [8 ]
Murray, Keith S. [8 ]
Abrahams, Brendan F. [1 ]
Harris, Hugh H. [9 ]
Sorace, Lorenzo [2 ,3 ]
Boskovic, Colette [1 ]
机构：
[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
[2] Univ Florence, UdR INSTM, I-50019 Sesto Fiorentino, FL, Italy
[3] Univ Florence, Dept Chem, I-50019 Sesto Fiorentino, FL, Italy
[4] Guglielmo Marconi Univ, Dept Appl Sci & Technol, I-00193 Rome, Italy
[5] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
[6] Australian Synchrotron, Clayton, Vic 3168, Australia
[7] KEK, Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan
[8] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[9] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 07期
基金：
澳大利亚研究理事会;
关键词：
DIOXOLENE COMPLEX; TETRAOXOLENE COMPLEX; CHARGE-DISTRIBUTION; INTERCONVERSION;
D O I：
10.1021/ic3002527
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A dinuclear cobalt complex with cobalt centers bridged by a bis(dioxolene) ligand exhibits a rare two-step valence tautomeric transition.
引用
收藏
页码：3944 / 3946
页数：3
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