3,5-Bis(acetaldehyde) substituted BODIPY

被引：20
|
作者：
Shandura, Mykola P. [1 ]
Yakubovskyi, Viktor P. [1 ]
Kovtun, Yuriy P. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 05期
关键词：
SINGLET OXYGEN GENERATION; BORON-DIPYRROMETHENE; PHOTODYNAMIC THERAPY; NUCLEOPHILIC-SUBSTITUTION; SPECTROSCOPIC PROPERTIES; FLUORESCENT-PROBE; DYES SYNTHESIS; FUNCTIONALIZATION; DERIVATIVES; BORADIAZAINDACENE;
D O I：
10.1039/c2ob27004h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two versions of a facile and efficient synthetic approach to 3,5-bis(acetaldehyde) substituted BODIPY have been developed and this compound has been used to obtain, in high yields, a variety of 3,5-divinyl BODIPY derivatives (vinylacetates, enamines, vinyl chlorides, and some multiple-functionalized products). As shown, vinyl substituents have an additive effect on the position of the BODIPY absorption maximum. The dyes synthesized are quite stable and exhibit intense absorption and fluorescence with wavelengths longer than 600 nm.
引用
收藏
页码：835 / 841
页数：7
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