Synthesis and characterization of Zn-doped mesoporous SnO2 by using thermally-stable block copolymer templates

被引：7

作者：

Suzuki, Norihiro ^{[1
]}

Imura, Masataka ^{[2
]}

Sato, Keisuke ^{[1
]}

Fukata, Naoki ^{[1
]}

Matsuura, Mikiya ^{[3
]}

Maekawa, Kazuhiko ^{[3
]}

Yamauchi, Yusuke ^{[1
,4
,5
]}

机构：

[1] Natl Inst Mat Sci, WPI Res Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan

[2] Natl Inst Mat Sci, Opt & Elect Mat Unit, Environment & Energy Mat Div, Tsukuba, Ibaraki 3050044, Japan

[3] Kuraray Co Ltd, Tsukuba Res Ctr, Polymer Mat Res Lab, Tsukuba, Ibaraki 3050841, Japan

[4] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Wako, Saitama 3510198, Japan

[5] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 18期

关键词：

MESOSTRUCTURED TIN OXIDE; THIN-FILMS; METAL-OXIDES; SENSITIZATION; FRAMEWORKS; MECHANISM;

D O I：

10.1039/c2dt32760k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using novel triblock copolymer templates, thermally-stable ordered mesoporous SnO2 thin films are synthesized through a solvent evaporation method. Owing to the high thermal stability of the triblock copolymer, the mesoporous structure is retained even after calcination at 600 degrees C. After the crystallization, the mesopore walls consist of small crystallite nanoparticles a few nanometers in diameter. By doping Zn species into the SnO2 framework, fine control of the crystallite sizes is successfully achieved. Under the optimized Zn content, the well-defined mesoporous structure is completely maintained after calcination at 600 degrees C.

引用

页码：6366 / 6373

页数：8

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