Triarylboron-based fluorescent conjugated microporous polymers

被引：31
|
作者：
Liu, Xiaoming [2 ]
Zhang, Yuwei [2 ]
Li, He [2 ]
Sigen, A. [2 ]
Xia, Hong [1 ]
Mu, Ying [2 ]
机构：
[1] Jilin Univ, Coll Elect Sci & Technol, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
来源：
RSC ADVANCES | 2013年 / 3卷 / 44期
基金：
中国国家自然科学基金;
关键词：
POROUS ORGANIC POLYMERS; SURFACE-AREA; SUPER-ABSORBENT; CARBON-DIOXIDE; FRAMEWORKS; HYDROGEN; GAS; LUMINESCENT; CATALYSIS; NETWORKS;
D O I：
10.1039/c3ra42801j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel triarylboron-based conjugatedmicroporous polymers (BCMPs) were successfully synthesized and characterized, which are insoluble in common organic solvents and water, and can keep stable up to 310 degrees C under a nitrogen atmosphere. According to the nitrogen physisorption isotherms, the Brunauer-Emmett-Teller specific surface area values for these porous materials vary between 815 and 911 m(2) g(-1). Two polymer frameworks display good carbon dioxide uptake capacity at 273 K and 1 bar. These materials might find applications in organic electronics and sensing technologies.
引用
收藏
页码：21267 / 21270
页数：4
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