First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X-H Bonds (X = N and O)

被引：47

作者：

Corberan, Rosa ^{[1
]}

Marrot, Sebastien ^{[2
]}

Dellus, Nicolas ^{[2
]}

Merceron-Saffon, Nathalie ^{[3
]}

Kato, Tsuyoshi ^{[2
]}

Peris, Eduardo ^{[1
]}

Baceiredo, Antoine ^{[2
]}

机构：

[1] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12080, Spain

[2] Univ Toulouse 3, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 09, France

[3] Univ Toulouse 3, FR Struct Federat Toulousaine Chim Mol 2599, F-31062 Toulouse 09, France

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 01期

关键词：

HETEROCYCLIC CARBENE COMPLEXES; COINAGE METAL-COMPLEXES; IMIDAZOLIUM SALT; LIGANDS; REACTIVITY; HEXAPHENYLCARBODIPHOSPHORANE; HYDROAMINATION; REARRANGEMENT; NHC; AU;

D O I：

10.1021/om8008958

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me,,S). The three complexes have been fully characterized, and their crystal structures have been determined. The two tert-butoxide complexes were tested in the catalytic anti-Markovnikov hydroamination and hydroalkoxylation of acrylonitrile, involving the first catalytic application of a carbodiphosphorane complex reported to date.

引用

页码：326 / 330

页数：5

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