Measurement of phase equilibria of supercritical carbon dioxide and paraffins

被引：70
|
作者：
Nieuwoudt, I [1 ]
du Rand, M [1 ]
机构：
[1] Univ Stellenbosch, Inst Thermal Separat Technol, Dept Chem Engn, ZA-7602 Matieland, South Africa
来源：
JOURNAL OF SUPERCRITICAL FLUIDS | 2002年 / 22卷 / 03期
关键词：
supercritical; phase equilibria; n-alkanes; carbon dioxide; equations of state;
D O I：
10.1016/S0896-8446(01)00122-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
High pressure phase equilibria of supercritical carbon dioxide with n-alkanes, n-C-12, n-C-16, n-C-20, n-C-24, n-C-28 and n-C-36, have been measured over the temperature range of 313-367 K, and are reported in this work. Of the various equations of state investigated, it was found that the Patel Teja equation of state provided the best fit of the CO2-n-alkane systems. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：185 / 199
页数：15
相关论文
共 50 条
  • [21] PHASE-EQUILIBRIA AND DISTRIBUTION COEFFICIENTS OF DELTA-LACTONES IN SUPERCRITICAL CARBON-DIOXIDE
    RIZVI, SSH
    YU, ZR
    BHASKAR, A
    ROSENBERRY, L
    JOURNAL OF FOOD SCIENCE, 1993, 58 (05) : 996 - 1000
  • [22] STUDIES ON PHASE-EQUILIBRIA OF A MULTICOMPONENT MODEL MIXTURE IN SUPERCRITICAL CARBON-DIOXIDE AND TRIFLUOROMETHANE
    PRANGE, MM
    RIEPE, WH
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 1987, 22 (04) : 183 - 191
  • [23] Addition and measurement of methanol in carbon dioxide mobile phase for supercritical fluid chromatography
    Pyo, D
    Lee, K
    Kim, H
    JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES, 1998, 21 (07) : 989 - 1002
  • [24] TERNARY PHASE EQUILIBRIA FOR ACETIC ACID-WATER MIXTURES WITH SUPERCRITICAL CARBON DIOXIDE.
    Briones, J.A.
    Mullins, J.C.
    Thies, M.C.
    Kim, B.-U.
    1600, (36):
  • [25] PHASE-EQUILIBRIA FOR SUPERCRITICAL EXTRACTION OF LEMON FLAVORS AND PALM OILS WITH CARBON-DIOXIDE
    MATHIAS, PM
    COPEMAN, TW
    PRAUSNITZ, JM
    FLUID PHASE EQUILIBRIA, 1986, 29 : 545 - 554
  • [26] Solubility measurement of α-asarone in supercritical carbon dioxide
    Chen, XQ
    Zhao, TS
    Yu, W
    FLUID PHASE EQUILIBRIA, 2003, 211 (01) : 11 - 15
  • [27] Experimental measurement on the viscosity of supercritical carbon dioxide
    Zhou, Yi
    Ni, Hongjian
    Shen, Zhonghou
    Liu, Weili
    MEASUREMENT, 2020, 151
  • [28] MEASUREMENT AND MODEL PREDICTION OF VAPOR LIQUID EQUILIBRIA OF MIXTURES OF RAPESEED OIL AND SUPERCRITICAL CARBON-DIOXIDE
    KLEIN, T
    SCHULZ, S
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1989, 28 (07) : 1073 - 1081
  • [29] Measurement and correlation of adsorption equilibria of propylene glycol monomethyl ether acetate on activated carbon in the presence of supercritical carbon dioxide
    Ushiki, Ikuo
    Tsuji, Hiromu
    Takishima, Shigeki
    Ito, Yasuyuki
    Sato, Yoshiyuki
    Inomata, Hiroshi
    FLUID PHASE EQUILIBRIA, 2020, 513 (513)
  • [30] ADSORPTION EQUILIBRIA OF BENZENE ON ACTIVATED CARBON IN THE PRESENCE OF SUPERCRITICAL CARBON-DIOXIDE
    SHOJIBARA, H
    SATO, Y
    TAKISHIMA, S
    MASUOKA, H
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1995, 28 (03) : 245 - 249
12345