Pyrrolate-catalyzed conjugate addition of pyrrole to electron-deficient alkenes

被引：5
|
作者：
Richardson, RD
Hernandez-Juan, FA
Dixon, DJ
机构：
[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[2] Univ Cambridge, Chem Labs, Cambridge CB2 1EW, England
来源：
SYNLETT | 2006年 / 01期
关键词：
conjugate addition; pyrrole; pyrrolate; catalysis; ligand acceleration;
D O I：
10.1055/s-2005-922777
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The conjugate addition of pyrrole as a nitrogen nucleophile can be catalyzed by potassium pyrrolate in coordinating solvents or by lithium pyrrolate in the presence of coordinating ligands offering an efficient route to protected P-amino carbonyl compounds.
引用
收藏
页码：77 / 80
页数：4
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