Potentiometric Study of Tungsten-Containing Chloride Melts

被引:0
|
作者
Ryzhov, A. A. [1 ]
Ivanov, A. B. [1 ]
Volkovich, V. A. [1 ]
Vasin, B. D. [1 ]
机构
[1] Ural Fed Univ, Dept Rare Met & Nanomat, Inst Phys & Technol, Ekaterinburg 620002, Russia
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D O I
10.1063/1.5002964
中图分类号
O59 [应用物理学];
学科分类号
摘要
Electrode potentials of tungsten were measured in the melts based on NaCl-2CsCl and 3LiCl-2KCl eutectic mixtures at 723-1123 K. Formal standard electrode potentials of tungsten in NaCl-2CsCl eutectic at 823-1123 K and 3LiCl-2KCl eutectic at 723-1123 K were determined from the experimental data. Temperature dependencies of the formal standard electrode potentials of tungsten and Gibbs free energy change of formation of tungsten tetrachloride in NaCl-2CsCl and 3LiCl-2KCl melts were obtained.
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页数:5
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