Bis(di-2-pyridylmethanediol-N,N')-palladium(II) dichloride tetrahydrate and dichloro(di-2-pyridylmethanediol-N,N')-gold(III) chloride

被引：15
|
作者：
Sommerer, SO
Jircitano, AJ
Westcott, BL
Abboud, KA
Bauer, JAK
机构：
[1] PENN STATE UNIV,BEHREND COLL,DIV SCI,ERIE,PA 16563
[2] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
[3] UNIV CINCINNATI,DEPT CHEM,CINCINNATI,OH 45221
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S0108270197000218
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Structural analyses of [Pd(C11H10N2O2)(2)]Cl-2 . 4H(2)O, (I), and [Au(C11H10N2O2)Cl-2]Cl, (II), revealed that both metals are in square-planar coordination environments. The Pd atom in (I) is coordinated equatorially by four N-atom donors and has two long-range Pd ... O interactions which lead to approximate pseudo-octahedral geometry. The Au complex achieves st coordination number of four with two N and two Cl donors, however, a weak long-range intramolecular axial interaction accounts for the fifth coordination site to make the species pseudo-square pyramidal.
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收藏
页码：707 / 710
页数：4
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