Identification of aerosol types over an urban site based on air-mass trajectory classification

Columnar aerosol properties retrieved from MICROTOPS II Sun Photometer measurements during 2010-2013 over Pune (18 degrees 32'N; 73 degrees 49'E, 559 m amsl), a tropical urban station in India, are analyzed to identify aerosol types in the atmospheric column. Identification/classification is carried out on the basis of dominant airflow patterns, and the method of discrimination of aerosol types on the basis of relation between aerosol optical depth (AOD(500) (nm),) and angstrom ngstrom exponent (AE, alpha). Five potential advection pathways viz., NW/N, SW/S, N, SE/E and L have been identified over the observing site by employing the NOAA-HYSPLIT air mass back trajectory analysis. Based on AE against AOD(500 nm), scatter plot and advection pathways followed five major aerosol types viz., continental average (CA), marine continental average (MCA), urban/industrial and biomass burning (UB), desert dust (DD) and indeterminate or mixed type (MT) have been identified. In winter, sector SE/E, a representative of air masses traversed over Bay of Bengal and Eastern continental Indian region has relatively small AOD (tau(p lambda) = 0.43 +/- 0.13) and high AE (alpha = 1.19 +/- 0.15). These values imply the presence of accumulation/submicron size anthropogenic aerosols. During pre-monsoon, aerosols from the NW/N sector have high AOD (tau(p lambda) = 0.61 +/- 0.21), and low AE (alpha = 0.54 +/- 0.14) indicating an increase in the loading of coarse-mode particles over Pune. Dominance of UB type in winter season for all the years (i.e. 2010-2013) may be attributed to both local/transported aerosols. During pre-monsoon seasons, MT is the dominant aerosol type followed by UB and DD, while the background aerosols are insignificant. (C) 2015 Elsevier B.V. All rights reserved.