Toward pillared layered metal sulfides. Intercalation of the chalcogenide clusters Co(6)Q(8)(PR(3))(6) (Q=S, Se, and Te and R=alkyl) into MoS2

被引：65

作者：

Bissessur, R

Heising, J

Hirpo, W

Kanatzidis, M

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

[2] MICHIGAN STATE UNIV,FUNCT MAT RES CTR,E LANSING,MI 48824

来源：

CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 02期

关键词：

D O I：

10.1021/cm950378+

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new family of materials based on layered transition metal dichalcogenides of the type [M'(x)Q(y)L(z)](n)[MoS2] (Q = S, Se, Te) was prepared as a first step toward pillared layered sulfides. The new intercalated phases form from the addition of Co(6)Q(8)(PR(3))(6) solutions to exfoliated suspensions MoS2.

引用

页码：318 / &

共 25 条

[21] Chalcogen-centered spirocyclic mixed-metal carbonyl complexes:: Synthesis and molecular structures of (CO)8(μ-PCy2)Re2(μ4-E)Fe2(μ-ER)(CO)6 and [(CO)8(μ-PCy2)Re2(μ4-E)Fe2(CO)6]2(μ4-E2) (E = S, Se, Te; R organic residue)
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ORGANOMETALLICS, 2003, 22 (17) : 3360 - 3366
[22] Regioselective addition of mixed-chalcogenide iron carbonyl clusters Fe-2(CO)(6)(mu-EE') (E not equal E', E, E'=S, Se, Te) to a carbon-carbon triple bond activated by a metal carbene fragment. Structural characterization of new trimetallic adducts Fe-2(CO)(6){mu-SC(Ph)=C(Te)[(OEt)C=Cr(CO)(5)]}, Fe-2(CO)(6-) {mu-SC(Ph)=C(Se)[(OEt)C=W(CO)(5)]}, and Fe-2(CO)(6){mu-SeC(Ph)=C(Te)[(OEt)C=W(CO)(5)]}
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ORGANOMETALLICS, 1997, 16 (15) : 3536 - 3540
[23] Zincselenide- and zinctelluride clusters with phenylselenolate and phenyltellurolate ligands.: The crystal structures of [NEt4]2[Zn4Cl4(SePh)6], [NEt4]2[Zn8Cl4Se(SePh)12], [Zn8Se(SePh)14(PnPr3)2], [HPnPr2R]2[Zn8Cl4Te(TePh)12] (R = nPr, Ph), and [Zn10Te4(TePh)12(PR3)2] (R = nPr, Ph)
Eichhofer, A
Fenske, D
Pfistner, H
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ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (11): : 1909 - 1914
[24] STRUCTURAL STUDY OF TRIANGULATED HETEROMETALLIC METAL-CLUSTERS WITH A MOLECULAR FRAGMENT (MU-PR2)RE2M IN RE2(MU-PR2)(CO)8[MU-M(CO)2PPH3] (M(I)=RH, IR, R=PH, CY) AND IN RE2RH(MU-CO)2(MU-PR2)(CO)6(PPH3)2 WITH A RHENIUM-RHODIUM DOUBLE-BOND
HAUPT, HJ
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INORGANIC CHEMISTRY, 1994, 33 (16) : 3481 - 3486
[25] Coupling of co-ordinated acetylide ligands with and without CO on chalcogen-stabilised mixed-metal clusters.: Synthesis and characterisation of [M2Fe3(L)2(CO)6(μ3-E)2{μ-CC(Ph)C(Ph)C}] and [M2Fe2(L)2(CO)4(μ3-E)2{μ-CC(Ph)(CO)C(Ph)C}] (L = η5-C5Me5 or η5-C5H5, M = Mo or W, E = S, Se or Te)
Mathur, P
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Dash, AK
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Puranik, VG
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (17): : 2916 - 2922

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