Toward pillared layered metal sulfides. Intercalation of the chalcogenide clusters Co(6)Q(8)(PR(3))(6) (Q=S, Se, and Te and R=alkyl) into MoS2

被引:65
|
作者
Bissessur, R
Heising, J
Hirpo, W
Kanatzidis, M
机构
[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824
[2] MICHIGAN STATE UNIV,FUNCT MAT RES CTR,E LANSING,MI 48824
关键词
D O I
10.1021/cm950378+
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new family of materials based on layered transition metal dichalcogenides of the type [M'(x)Q(y)L(z)](n)[MoS2] (Q = S, Se, Te) was prepared as a first step toward pillared layered sulfides. The new intercalated phases form from the addition of Co(6)Q(8)(PR(3))(6) solutions to exfoliated suspensions MoS2.
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页码:318 / &
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