Spectroscopic analysis of an unusual Ca•Xe[3Σ-]←Ca(4s4pπ 3P0)•Xe[3Π0-] transition

被引：2

作者：

Leung, AWK ^{[1
]}

Bellert, D ^{[1
]}

Breckenridge, WH ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 14期

关键词：

D O I：

10.1063/1.480020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From the partially resolved rotational structure of six vibrational bands at high resolution, a vibrational progression in the 22 400-22 900 cm(-1) region has been assigned to a CaXe[(3)Sigma(-)]<-- Ca(4s4p pi P-3(0)). Xe[(3)Pi(0)(-)] transition. It is suggested that the CaXe[(3)Sigma(-)] state observed is a "mixed" state, having both Ca(4p pi 4p pi P-3(J)). Xe[(3)Sigma(-)] and Ca(3d pi 4p pi D-3(J)). Xe[(3)Sigma(-)] character due to an adiabatic avoided crossing between the two diabatic states. (C) 1999 American Institute of Physics. [S0021-9606(99)02938-4].

引用

页码：6434 / 6438

页数：5

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