Structure of amorphous P-Se prepared by mechanical alloying

被引:2
|
作者
Itoh, K
Misawa, M
Fukunaga, T
机构
[1] Kyoto Univ, Inst Res Reactor, Osaka 5900494, Japan
[2] Niigata Univ, Fac Sci, Dept Chem, Niigata 9502181, Japan
关键词
D O I
10.1016/S0022-3093(02)01772-6
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The short- and medium-range structures of amorphous P1-xSex (x = 0.6, 0.8) synthesized by mechanical alloying (MA) have been investigated by time-of-flight neutron diffraction. The first diffraction peak, near Q = 12 nm(-1) in the structure factor, S(Q), which is strongly related to the medium range order, is smaller in height and broader in width than that for amorphous P1-xSex (x = 0.6, 0.8) prepared by liquid quenching. The formation of the medium-range order is restrained when the amorphous P-Se is synthesized by MA. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:561 / 565
页数:5
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