0 Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction

被引：7

作者：

Mifleur, Alexis ^{[1
]}

Mortreux, Andre ^{[1
]}

Suisse, Isabelle ^{[1
]}

Sauthier, Mathieu ^{[1
]}

机构：

[1] Univ Artois, Univ Lille, CNRS,Cent Lille, ENSCL,UMR8181,UCCS,Unite Catalyse & Chim Solide, F-59000 Lille, France

来源：

MOLECULAR CATALYSIS | 2017年 / 427卷

关键词：

SOLVO-SURFACTANTS; ETHERIFICATION; TELOMERIZATION; CHEMICALS; FUEL; TRANSFORMATION; 1,3-BUTADIENE; DERIVATIVES; ISOBUTENE; ADDITIVES;

D O I：

10.1016/j.molcata.2016.11.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining 100% glycerol conversion into a mixture of glyceryl mono-and dibutenyl ethers. The experimental protocols used involved batch experiments or continuous feeding of butadiene at atmospheric pressure. The reaction has then been scaled up to produce multigrams of each pure monoethers and diethers according to simple decantation/distillation procedures. The ethers were further hydrogenated to their corresponding alkyl glyceryl ethers. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：25 / 30

页数：6

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