N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex-Catalyzed Suzuki-Miyaura Coupling of Aryl Sulfonates with Arylboronic Acids

被引：82

作者：

Wang, Zhan-Yong ^{[1
]}

Chen, Gao-Qi ^{[1
]}

Shao, Li-Xiong ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 15期

关键词：

PALLADIUM COMPLEXES; IM=1-METHYLIMIDAZOLE COMPLEXES; HETEROARYL MESYLATES; NHC-PD(II)-IM NHC; CARBENE LIGANDS; CROSS-COUPLINGS; BOND FORMATION; CHLORIDES; TOSYLATES; PHOSPHINE;

D O I：

10.1021/jo301270t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also be achieved even by using the less reactive mesylates as the substrates. It is worthy of noting here that this is the first example of NHC-Pd(II) complex-catalyzed Suzuki-Miyaura coupling of aryl sulfonates with arylboronic acids, enriching an inexpensive, convenient, and alternative method for the synthesis of biaryl compounds.

引用

页码：6608 / 6614

页数：7

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