A room temperature spin crossover ionic liquid

被引：17
|
作者：
Fitzpatrick, Anthony J. [1 ]
O'Connor, Helen M. [1 ]
Morgan, Grace G. [1 ]
机构：
[1] Sch Chem, Dublin 4, Ireland
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 48期
基金：
爱尔兰科学基金会;
关键词：
MANGANESE(III) COMPLEX; STATE; TRANSITION;
D O I：
10.1039/c5dt04264j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(III) or manganese(III) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states. Both are liquids at room temperature and the Fe(III) based IL exhibits a spin crossover close to 300 K. The spin crossover profile is independent of the solvation, and is both air and moisture stable.
引用
收藏
页码：20839 / 20842
页数：4
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