1,6-epithio- and 1,6-episeleno-beta-D-glucopyranose: Useful adjuncts in the synthesis of 6-deoxy-beta-D-glucopyranosides

被引:8
|
作者
Stick, RV
Tilbrook, DMG
Williams, SJ
机构
[1] Department of Chemistry, University of Western Australia, Nedlands
基金
澳大利亚研究理事会;
关键词
D O I
10.1016/S0040-4039(97)00458-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The treatment of derivatives of 1,6-epithio- and 1,6-episeleno-beta-D-glucopyranose with various carbohydrate alcohols in the presence of N-iodosuccinimide/triflic acid gives rise to di sulfides and diselenides, respectively, which may be transformed to the desired 6-deoxy-beta-D-glucopyranosides. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:2741 / 2744
页数:4
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