Hydrothermal synthesis and crystal structure of a layered coordination polymer:: [Zn3(C2O4)3(4,4′-bipy)4]n (4,4′-bipy=4,4′-bipyridine)

被引：21

作者：

Hao, N ^{[1
]}

Shen, EH ^{[1
]}

Li, YG ^{[1
]}

Wang, EB ^{[1
]}

Hu, CW ^{[1
]}

Xu, L ^{[1
]}

机构：

[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 691卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

coordination polymer; metal-organic; hydrothermal synthesis; crystal structure;

D O I：

10.1016/j.molstruc.2004.01.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An interesting metal-organic coordination polymer {[Zn-3(C2O4)(3)(4,4'-bipy)(4)]}(n) 1 has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TG analysis, and single-crystal X-ray diffraction. Compound I crystallizes in the monoclinic system, space group P2(1)/c, a = 16.264(3) Angstrom, b = 15.603(3) Angstrom, c = 16.343(3) Angstrom, beta = 94.13(3)degrees, V = 4136.5(14) Angstrom(3), Z = 4, R1 = 0.0554, wR(2) = 0.1217. Compound 1 exhibits a 2D network, which consists of infinite zinc (II) oxalate chains connected to each other by a half of 4,4'-bipy acting as bridging ligands, while the other half of 4,4-bipy just does as terminal ones. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：273 / 277

页数：5

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