Carbenic philicity and the 'intrinsic reactivity index'

被引：12
|
作者：
Moss, Robert A. [1 ]
Krogh-Jespersen, Karsten [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, New Brunswick, NJ 08903 USA
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 32期
基金：
美国国家科学基金会;
关键词：
Frontier molecular orbital energies; Reactivity indices; Singlet carbenes; SINGLET CARBENES; ELECTROPHILICITY; NUCLEOPHILICITY; SELECTIVITY;
D O I：
10.1016/j.tetlet.2013.06.007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactivity of electrophilic, ambiphilic, and nucleophilic singlet carbenes is considered in terms of a recently proposed 'intrinsic reactivity index' (IRI). Comparisons of IRI are made with previously described analyses, and it is concluded that IRI is not as useful for the determination or analysis of carbene philicity as FMO-based or empirical treatments. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4303 / 4305
页数：3
相关论文
共 50 条
  • [21] Backbone-functionalized imidazol-2-ylidenes: Towards novel reactivity and carbenic architectures
    Cesar, Vincent
    Benhamou, Laure
    Vujkovic, Nadia
    Tourneux, Jean-Christophe
    Brousses, Remy
    Lugan, Noel
    Lavigne, Guy
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [22] INTRINSIC REACTIVITY OF CARBONS TO OXYGEN
    JAMALUDDIN, AS
    TRUELOVE, JS
    WALL, TF
    FUEL, 1983, 62 (04) : 484 - 486
  • [23] INTRINSIC REACTIVITY OF CARBONS TO OXYGEN
    SMITH, IW
    FUEL, 1978, 57 (07) : 409 - 414
  • [24] Philicity scales using molecular quantum similarity and chemical reactivity indices within density functional theory
    Morales-Bayuelo, Alejandro
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2023, 123 (21)
  • [25] Understanding the Intrinsic Reactivity of Black Phosphorus
    Tian, Haijiang
    Wang, Haoyu
    Wang, Jiahong
    Qu, Guangbo
    Yu, Xue-Feng
    Jiang, Guibin
    ACCOUNTS OF MATERIALS RESEARCH, 2024,
  • [26] INTRINSIC REACTIVITY OF PETROLEUM COKE TO OXYGEN
    TYLER, RJ
    FUEL, 1986, 65 (02) : 235 - 240
  • [27] STERIC EFFECTS ON THE INTRINSIC REACTIVITY OF NITROTRIPHENYLMETHANES
    TERRIER, F
    BOUBAKER, T
    XIAO, L
    FARRELL, PG
    JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (14): : 3924 - 3929
  • [28] Intrinsic Religiosity and Physiological Reactivity to Stress
    Witham, Alyssa
    Koci, Amanda
    Coenen, Madeleine
    Fox, Sheilagh
    Austin, Tara
    DeBarros, Andrea
    Wheeler, Louise
    Caldwell, Yoko
    Brown, Tracy
    Steffen, Patrick
    Cress, Nikki
    Brown, Brodrick
    APPLIED PSYCHOPHYSIOLOGY AND BIOFEEDBACK, 2016, 41 (04) : 432 - 432
  • [29] Intrinsic reactivity index as a single scale directed toward both electrophilicity and nucleophilicity using frontier molecular orbitals
    Kiyooka, Syun-ichi
    Kaneno, Daisuke
    Fujiyama, Ryoji
    TETRAHEDRON, 2013, 69 (21) : 4247 - 4258
  • [30] A NEW REACTIVITY INDEX——PSEUDO ORBITAL INDEX
    Fu Jiang DING~*
    ChineseChemicalLetters, 1991, (12) : 975 - 978
12345