Carbenic philicity and the 'intrinsic reactivity index'

被引：12
|
作者：
Moss, Robert A. [1 ]
Krogh-Jespersen, Karsten [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, New Brunswick, NJ 08903 USA
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 32期
基金：
美国国家科学基金会;
关键词：
Frontier molecular orbital energies; Reactivity indices; Singlet carbenes; SINGLET CARBENES; ELECTROPHILICITY; NUCLEOPHILICITY; SELECTIVITY;
D O I：
10.1016/j.tetlet.2013.06.007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactivity of electrophilic, ambiphilic, and nucleophilic singlet carbenes is considered in terms of a recently proposed 'intrinsic reactivity index' (IRI). Comparisons of IRI are made with previously described analyses, and it is concluded that IRI is not as useful for the determination or analysis of carbene philicity as FMO-based or empirical treatments. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4303 / 4305
页数：3
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