Macropolyhedral boron-containing cluster chemistry. Nineteen-vertex [S2B17H17(SMe(2))]. An unusual apical boron atom of cluster connectivity six that introduces a new polyhedral borane building block

被引：19

作者：

Kaur, P

Holub, J

Rath, NP

Bould, J

Barton, L

Stibr, B

Kennedy, JD

机构：

[1] ACAD SCI CZECH REPUBL,INST INORGAN CHEM,CR-25068 REZ,CZECH REPUBLIC

[2] UNIV MISSOURI,DEPT CHEM,ST LOUIS,MO 63121

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mild thermolysis of [SB8H10(SMe(2))] results in the formation of a small amount of macropolyhedral [S2B17H17(SMe(2))] of which the structure is based on the fusion, with two boron atoms in common, of a conventional nido-type eleven-vertex {SB10H9} subcluster with an unprecedented arachno-type ten-vertex {SB9H8(SMe(2))} subcluster that exhibits an apical boron atom of cluster connectivity six.

引用

页码：273 / 275

页数：3

共 43 条

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Shea, SL
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INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (04) : 169 - 172
[32] Macropolyhedral boron-containing cluster chemistry.: The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)2] to give [(PMe2Ph)2PtB16H17Me] and [(PMe2Ph)2PtB14H16]
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DALTON TRANSACTIONS, 2005, (08) : 1499 - 1503
[33] Macropolyhedral boron-containing cluster chemistry. Novel intercluster linkages from the reaction of [Pt(cod)CI2] and [PtMe2(PMe2Ph)2] with 6,6'-(B10H13)2]
Bould, Jonathan
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CHEMICAL COMMUNICATIONS, 2007, (47) : 5084 - 5086
[34] Macropolyhedral boron-containing cluster chemistry.: Intermolecular coordination via hydrogen-metal interaction.: The solvent-free synthesis and dimeric constitution of [pd2b36h40(pme2ph)4]
Londesborough, Michael G. S.
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COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2007, 72 (12) : 1639 - 1645
[35] Macropolyhedral boron-containing cluster chemistry products of the reaction between [{Ru(η6-MeC6H4isoPr)Cl2}2] and syn-[B18H22].: A syn → anti 18-vertex configurational change
Shea, SL
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INORGANICA CHIMICA ACTA, 2005, 358 (05) : 1709 - 1714
[36] Macropolyhedral boron-containing cluster chemistry. Assessment of the possibilities of thermolytic mixed-cluster fusion, and of the use of synchrotron X-radiation for the examination of small single crystals of metallaboranes. Isolation and structure of eighteen-vertex [7-(CO)-7,7-(PMe3)(2)-syn-7-IrB17H20]
Bould, J
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (12): : 2005 - 2007
[37] Macropolyhedral boron-containing cluster chemistry. Isolation and characterisation of the eighteen-vertex nido-5'-iridaoctaborano[3',8':1,2]-closo-4-iridadodecaborane, [(Co)(PMe(3))(2)IrB16H14Ir(CO)(PMe(3))(2)]
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (14): : 3145 - 3149
[38] Macropolyhedral boron-containing cluster chemistry.: Ligand-induced two-electron variations of intercluster bonding intimacy.: Structures of nineteen-vertex[(η5-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(η5-C5Me5)HIrB18H19{C(NHMe)2}]
Shea, SL
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Stíbr, B
Thornton-Pett, M
Kennedy, JD
DALTON TRANSACTIONS, 2004, (10) : 1521 - 1523
[39] Macropolyhedral boron-containing cluster chemistry.: Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(η5-C5Me5)}2].: Synchrotron X-ray structures of [(η5-C5Me5)2Ir2B16H17Cl] and [(η5-C5Me5)2Ir2B16H15Cl]
Carr, Michael J.
Perera, Sarath D.
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Clegg, William
Stibr, Bohumil
Kennedy, John D.
DALTON TRANSACTIONS, 2006, (44) : 5221 - 5224
[40] Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B18H22 borane cluster:: molecular structures of [Ni(THF)4(H2O)2][B18H20Ni(η5-C5H5)]2 and [B18H19(2-THF)Ni(η5-C5H5)]
Taylor, JW
Englich, U
Ruhlandt-Senge, K
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (17): : 3392 - 3397

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