Copper-mediated C-H trifluoromethylation of quinones

被引：82
|
作者：
Ilchenko, Nadia O. [1 ]
Janson, Par G. [1 ]
Szabo, Kalman J. [1 ]
机构：
[1] Stockholm Univ, Dept Organ Chem, SE-10691 Stockholm, Sweden
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 59期
关键词：
ELECTROPHILIC TRIFLUOROMETHYLATION; CATALYZED TRIFLUOROMETHYLATION; TERMINAL ALKENES; HYDROTRIFLUOROMETHYLATION; FLUORINE; ARENES;
D O I：
10.1039/c3cc43357a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Quinones undergo copper-mediated C-H trifluoromethylation reactions using a hypervalent iodine reagent. The reactions have a broad synthetic scope involving naphtho, alkyl, chloro and methoxy quinones.
引用
收藏
页码：6614 / 6616
页数：3
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