Modification of Pyrolytic Oil from Waste Tyres as a Promising Method for Light Fuel Production

被引:22
|
作者
Debek, Cezary [1 ]
机构
[1] Inst Engn Polymer Mat & Dyes, Dept Elastomers & Rubber Technol, Harcerska 30 St, PL-05820 Piastow, Poland
来源
MATERIALS | 2019年 / 12卷 / 06期
关键词
tyre pyrolysis; rubber; pyrolytic oil; hydrorefining; hydrodesulphurization; light fuel oil;
D O I
10.3390/ma12060880
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Due to its high total sulphur content and other unfavourable properties, pyrolytic oil obtained as a result of tyres pyrolysis is not suitable for use as motor or heating fuel. Therefore, pyrolytic oil was hydrorefined. Hydrorefined oil was used as a component of light heating oil. A composition was prepared from 30 wt % hydrorefinate with 70 wt % Ekoterm Plus (a commercial oil). Unfortunately, the flash point temperature of the hydrorefinate was too low, and did not allow fuel compliant with the Polish standard PN-C-96024:2011 for L1 light heating oil to be obtained. Therefore, the fraction with boiling point below 180 degrees C was removed from the hydrorefinate. The residue, with a flash point of 74 degrees C and a sulphur content of 0.143 wt %, was mixed with Ekoterm Plus and fuels with a hydrorefinate fraction content of 30 and 50 wt % were prepared. The composition containing 30 wt % met the requirements for L1 oil in the whole range of tested parameters. Total sulphur content was 0.092 wt %, specific weight was 856 kg/m(3) and closed cup flash point was 64 degrees C. However, the composition containing 50 wt % hydrorefinate did not meet the requirements regarding sulphur content and specific weight. Sulphur content, specific gravity, and flash point are the parameters limiting the possibility of using hydrorefined pyrolytic oil for composing light heating oils compliant with the mentioned standard.
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页数:8
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