Chromium(II)-catalyzed enantioselective arylation of ketones

被引：4
|
作者：
Wang, Gang [1 ,2 ]
Sun, Shutao [2 ]
Mao, Ying [2 ]
Xie, Zhiyu [2 ]
Liu, Lei [1 ,2 ,3 ]
机构：
[1] Shandong Univ, Shenzhen Res Inst, Shenzhen 518057, Peoples R China
[2] Shandong Univ, Sch Pharmaceut Sci, Jinan 250012, Peoples R China
[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 12卷
基金：
美国国家科学基金会;
关键词：
arylation; asymmetric catalysis; chromium; ketone; tertiary alcohol; NOZAKI-HIYAMA ALLYLATION; MEDIATED COUPLING REACTIONS; FREE-ENERGY RELATIONSHIPS; ASYMMETRIC CATALYSIS; ORGANOCHROMIUM REAGENTS; CHROMIUM CATALYSIS; KISHI REACTION; LIGAND; ALDEHYDES; HALIDES;
D O I：
10.3762/bjoc.12.275
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The chromium-catalyzed enantioselective addition of carbo halides to carbonyl compounds is an important transformation in organic synthesis. However, the corresponding catalytic enantioselective arylation of ketones has not been reported to date. Herein, we report the first Cr-catalyzed enantioselective addition of aryl halides to both arylaliphatic and aliphatic ketones with high enantioselectivity in an intramolecular version, providing facile access to enantiopure tetrahydronaphthalen-1-ols and 2,3-dihydro-1H-inden-1-ols containing a tertiary alcohol.
引用
收藏
页码：2771 / 2775
页数：5
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