Integrity and structural characteristics of the M6E8 (E = S, Se, Te) cluster core:: Syntheses and structures of [Co6S8(PR3)6]n+ (R = Me2Ph, n = 1; R = OMe, n = 0)

被引：5
|
作者：
Kang, BS [1 ]
Wen, TB
Yu, XY
Zhang, HX
Tong, YX
Su, CY
Chen, ZN
Liu, HQ
机构：
[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 1999年 / 10卷 / 03期
基金：
中国国家自然科学基金;
关键词：
cluster core M6E8; structural characteristics; crystal structure; hexacobalt cluster complex; phosphine; sulfide bridging;
D O I：
10.1023/A:1022681127451
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new members of the hexanuclear series [Co6S8(PR3)(6)](n+). complexes [Co6S8(PMe2Ph)(6)](ClO4) (1) and [Co6S8{P(OMe)(3)}(6)] (2), have been syn thesizes and characterized by X-ray diffraction analyses. Their formation process was postulated to go through trinuclear mu(3)-S bridged moieties. The structural characterisitics of the M6E8P6 skeleton of a whole series of [M6E8(PR3)(6)](n+) (M = Co, Cr, Fe, Mo; E = S, Se, Te) complexes are presented in terms of atomic distances and core volumes.
引用
收藏
页码：429 / 443
页数：15
相关论文
共 50 条
  • [31] Synthesis and characterization of group 14 dialkylmetal chalcogenones RN2M=E [RN = CH(SiMe3)C9H6N-8 or CPh(SiMe3)C5H4N-2; M = Ge or Sn; E = S, Se, or Te]
    Leung, WP
    Kwok, WH
    Zhou, ZY
    Mak, TCW
    ORGANOMETALLICS, 2000, 19 (03) : 296 - 303
  • [32] Hydrogen bonds in radical cation salts of TTF(CH2OH)4:: First complete series with the octahedral rhenium cluster anions [Re6S8-nCl6+n]n-4 (n=0, 1, 2, 3)
    Perruchas, S
    Boubekeur, K
    Batail, P
    CRYSTAL GROWTH & DESIGN, 2005, 5 (04) : 1585 - 1596
  • [33] Reactions of a ditungsten-capped tetrayne with cobalt carbonyls:: molecular structures of {W(CO)3Cp}2{μ-C8[Co2(μ-dppm)m(CO)6-2m]n} (m = 0, 1; n = 1, 2)
    Brace, MI
    Kelly, BD
    Skelton, BW
    White, AH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (06): : 847 - 852
  • [34] Solvothermal Syntheses, Crystal Structures and Selected Optical Properties of [M(C8N5H23)]2Sn2S6 (M =Co, Fe, Ni; C8N5H23 = tetraethylenepentamine)
    Pienack, Nicole
    Lehmann, Stefanie
    Luehmann, Henning
    El-Madani, Marzog
    Naether, Christian
    Bensch, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (12-13): : 2323 - 2329
  • [35] Phosphine-substituted diiron complexes Fe2(μ-Rodt)(CO)6-n(PPh3)n (R = Ph, Me, H and n=1, 2) featuring desymmetrized oxadithiolate bridges: structures, protonation, and electrocatalysis
    Gu, Xiao-Li
    Li, Jian-Rong
    Jin, Bo
    Guo, Yang
    Jing, Xing-Bin
    Zhao, Pei-Hua
    NEW JOURNAL OF CHEMISTRY, 2021, 45 (38) : 17996 - 18007
  • [36] Reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E = S, Se) with azides.: Synthesis of (μ-RE)(μ-p-R1C6H4N3H)Fe2(CO)6 and crystal structure of (μ-ButS)(μ-PhN3H)Fe2(CO)6
    Wang, ZX
    Miao, SB
    Zhou, ZY
    Zhou, XG
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 601 (01) : 87 - 92
  • [37] Experimental and theoretical comparison of actinide and lanthanide bonding in M[N(EPR2)2]3 complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H)
    Gaunt, Andrew J.
    Reilly, Sean D.
    Enriquez, Alejandro E.
    Scott, Brian L.
    Ibers, James A.
    Sekar, Perumal
    Ingram, Kieran I. M.
    Kaltsoyannis, Nikolas
    Neu, Mary P.
    INORGANIC CHEMISTRY, 2008, 47 (01) : 29 - 41
  • [38] A series of soluble, discrete homo and heteroleptic Ca(II) complexes of hexanuclear sulfidochloride rhenium clusters, [Ca(X)n(Y)m][Re6S6Cl8], (n=6, m=0, X = DMF, THF, DMSO; n=4, m=3, X = MeCN, Y = THF, dioxane) and the 1D co-ordination polymer [Ca(MeCN)3(OH2)2(dioxane)2]- [Re6S6Cl8]•(dioxane)(MeCN)
    Perruchas, S
    Simon, F
    Uriel, S
    Avarvari, N
    Boubekeur, K
    Batail, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 643 : 301 - 306
  • [39] Chalcogen-centered spirocyclic mixed-metal carbonyl complexes:: Synthesis and molecular structures of (CO)8(μ-PCy2)Re2(μ4-E)Fe2(μ-ER)(CO)6 and [(CO)8(μ-PCy2)Re2(μ4-E)Fe2(CO)6]2(μ4-E2) (E = S, Se, Te; R organic residue)
    Klose, S
    Flörke, U
    Egold, H
    ORGANOMETALLICS, 2003, 22 (17) : 3360 - 3366
  • [40] (S)-8-CDI-N-PROPYLAMINO)-6,7,8,9-TETRAHYDRO-3H-BENZ[E]INDOLE-1-CARBALOEHYDE AND (R)-8-(DI-N-PROPYLAMINO)-6,7,8,9-TETRAHYDRO-3H-BENZ[E]INDOLE-1-CARBALDEHYDE - A NEW CLASS OF ORALLY-ACTIVE 5-HT1A-RECEPTOR AGONISTS
    STJERNLOF, P
    GULLME, M
    ELEBRING, T
    ANDERSSON, B
    WIKSTROM, H
    LAGERQUIST, S
    SVENSSON, K
    EKMAN, A
    CARLSSON, A
    SUNDELL, S
    JOURNAL OF MEDICINAL CHEMISTRY, 1993, 36 (15) : 2059 - 2065
12345