2(2-hydroxyphenyl)2H-benzotriazole ultraviolet stabilizers

被引：88
|
作者：
Crawford, JC [1 ]
机构：
[1] Rohm & Haas Co, Res Labs, Spring House, PA 19477 USA
来源：
PROGRESS IN POLYMER SCIENCE | 1999年 / 24卷 / 01期
关键词：
2(2-Hydroxyphenyl)H-benzotriazole; ultraviolet stabilizers; stabilizing additives;
D O I：
10.1016/S0079-6700(98)00012-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
2(2-hydroxyphenyl)2H-benzotriazole ultraviolet stabilizers are now the most prominent and effective stabilizers for plastics materials, especially automotive coatings. This article provides a comprehensive review of the synthesis, photochemistry and photophysics of 2(2-hydroxyphenyl)2H-benzotriazole ultraviolet stabilizers. New approaches for optimization of UV stabilization using grafting, compatibilization, polymerizable stabilizers and polymer bound stabilizers are emphasized. A brief overview of surface active stabilization and stabilization of polymer blends is presented. Economic considerations, worldwide consumption estimates and commercial applications of this unique class of ultraviolet light stabilizers are among the topics discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7 / 43
页数：37
相关论文
共 50 条
  • [21] FUNCTIONAL POLYMERS .45. INCORPORATION OF DIHYDROXY "2(2-HYDROXYPHENYL)H-2-BENZOTRIAZOLE DERIVATIVES INTO POLYESTERS
    GOMEZ, PM
    VOGL, O
    POLYMER JOURNAL, 1986, 18 (05) : 429 - 437
  • [22] Novel structural modifications associated with the highly efficient internal conversion of 2-(2'-hydroxyphenyl)benzotriazole ultraviolet stabilizers
    Estevez, CM
    Bach, RD
    Hass, KC
    Schneider, WF
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (23) : 5445 - 5446
  • [23] FUNCTIONAL POLYMERS .16. SYNTHESIS AND POLYMERIZATION OF 2(2-HYDROXY-5-ISOPROPENYLPHENYL)-2H-BENZOTRIAZOLE AND A NEW SYNTHESIS OF 2(2-HYDROXY-5-VINYLPHENYL)2H-BENZOTRIAZOLE
    NIR, Z
    VOGL, O
    GUPTA, A
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (10) : 2735 - 2754
  • [24] DEACTIVATION PROCESSES OF ULTRAVIOLET STABILIZERS OF THE 2-(HYDROXYPHENYL)BENZOTRIAZOLE CLASS WITH INTRAMOLECULAR HYDROGEN-BONDS
    GOELLER, G
    RIEKER, J
    MAIER, A
    STEZOWSKI, JJ
    DALTROZZO, E
    NEUREITER, M
    PORT, H
    WIECHMANN, M
    KRAMER, HEA
    JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (06): : 1452 - 1458
  • [25] MODE OF ACTION OF STABILIZERS IN POLYMERS CONSIDERING 2-HYDROXYPHENYL BENZOTRIAZOLES
    KRAMER, HEA
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1990, 183 : 67 - 101
  • [26] FUNCTIONAL POLYMERS .60. CHEMICAL-STRUCTURE ULTRAVIOLET-SPECTRUM RELATIONSHIP OF 2(2-HYDROXYPHENYL)2H-BENZOTRIAZOLES - SYNTHESIS OF NOVEL 2(2-HYDROXYPHENYL)2H-BENZOTRIAZOLES
    SUSTIC, A
    VOGL, O
    POLYMER, 1995, 36 (17) : 3401 - 3408
  • [27] Synthesis of 2-(2'-acetoxy-5'-bromomethylphenyl)-2H-benzotriazole
    Ma, Wei
    Liu, Yong
    Zhang, Shufen
    Huagong Xuebao/CIESC Journal, 2010, 61 (11): : 2992 - 2998
  • [28] PHOTOPHYSICAL DEACTIVATION PROCESSES OF ULTRAVIOLET STABILIZERS OF THE 2-(HYDROXYPHENYL)BENZOTRIAZOLE CLASS WITH INTRAMOLECULAR HYDROGEN-BONDS
    KRAMER, HEA
    WERNER, T
    WOESSNER, G
    GOELLER, G
    RIEKER, J
    STEZOWSKI, JJ
    KOLLAT, P
    HOIER, H
    MAIER, A
    HAUSER, M
    KLEIN, UKA
    DALTROZZO, E
    NEUREITER, M
    JOURNAL OF INFORMATION RECORDING MATERIALS, 1989, 17 (5-6): : 449 - 458
  • [29] FUNCTIONAL POLYMERS .59. SYNTHESIS AND POLYMERIZATION OF 2(2-HYDROXYPHENYL)2H-BENZOTRIAZOLE-BASED GLYCIDYL METHACRYLATE DERIVATIVES
    SUSTIC, A
    ZHANG, CL
    VOGL, O
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1993, A30 (9-10): : 741 - 755
  • [30] FUNCTIONAL POLYMERS .61. ULTRAVIOLET SPECTRAL BEHAVIOR OF SELECTED 2(2-HYDROXYPHENYL)2H-BENZOTRIAZOLES
    SUSTIC, A
    FALCETTA, J
    SMITH, C
    QIN, MF
    VOGL, O
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1995, A32 (8-9): : 1601 - 1611
12345