Reusable polymer-supported catalyst for the [3+2] Huisgen cycloaddition in automation protocols

被引：284
|
作者：
Girard, C
Önen, E
Aufort, M
Beauvière, S
Samson, E
Herscovici, J
机构：
[1] Ecole Natl Super Chim Paris, F-75005 Paris, France
[2] INSERM, U640, F-75006 Paris, France
[3] CNRS, UMR8151, F-75006 Paris, France
[4] Univ Paris 05, Fac Pharm, Unite Pharmacol Chim & Genet, F-75270 Paris, France
[5] CNRS, Chim Mol Paris Ctr, F-75005 Paris, France
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 08期
关键词：
D O I：
10.1021/ol060283l
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A polymer-supported catalyst for Huisgen's [3+2] cycloaddition reaction between azides and alkynes was prepared from copper(I) iodide and Amberlyst A-21. This catalyst was then used in an automated synthesis of 1,4-disubstituted 1,2,3-triazoles giving access to these products in good yields. The catalyst has shown good activity, stability, and recycling capabilities.
引用
收藏
页码：1689 / 1692
页数：4
相关论文
共 50 条
  • [41] Preparation of biohybrid amphiphiles via the copper catalysed Huisgen [3+2] dipolar cycloaddition reaction
    Dirks, AJT
    van Berkel, SS
    Hatzakis, NS
    Opsteen, JA
    van Delft, FL
    Cornelissen, JJLM
    Rowan, AE
    van Hest, JCM
    Rutjes, FPJT
    Nolte, RJM
    CHEMICAL COMMUNICATIONS, 2005, (33) : 4172 - 4174
  • [42] Lignin Nanosphere-Supported Cuprous Oxide as an Efficient Catalyst for Huisgen [3+2] Cycloadditions under Relatively Mild Conditions
    Zhou, Zidan
    Peng, Xinwen
    Zhong, Linxin
    Li, Xuehui
    Sun, Runcang
    POLYMERS, 2018, 10 (07)
  • [43] CO2-Based Carbamate Synthesis Utilizing Reusable Polymer-Supported DBU
    Vargas, Jorge Andres Mora
    Burtoloso, Antonio C. B.
    CHEMSUSCHEM, 2023, 16 (23)
  • [44] A reusable polymer supported catalyst for copper-azide-alkyne cycloaddition (CuAAC) under ambient conditions
    Arya, Suku
    Asiya, Abdul Shiyas
    Anas, Saithalavi
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (40) : 17385 - 17390
  • [45] Nucleophilic polymer-supported tertiaryphosphine organocatalysis: [3+2] annulation reaction of alkyl 2-butynoates with activated alkenes
    Hailing Liu
    Chemical Research in Chinese Universities, 2014, 30 : 593 - 595
  • [46] POLYMER-SUPPORTED BASES .3. SYNTHESIS OF PHOSPHATIDYLCHOLINES USING POLYMER-SUPPORTED AMINOPYRIDINES
    TOMOI, M
    GOTO, M
    KAKIUCHI, H
    NOGUCHI, Y
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1985, 6 (06): : 397 - 401
  • [47] Reusable polymer-supported amine-copper catalyst for the formation of α-alkylidene cyclic carbonates in Supercritical carbon dioxide
    Jiang, Huan-Feng
    Wang, A-Zhong
    Liu, Hai-Ling
    Qi, Chao-Rong
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (13) : 2309 - 2312
  • [48] Microencapsulated palladium catalysts: Allylic substitution and Suzuki coupling using a recoverable and reusable polymer-supported palladium catalyst
    Akiyama, R
    Kobayashi, S
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (18) : 3469 - +
  • [49] A POLYMER-SUPPORTED DICHLORO(CYCLOPENTADIENYL)RHODIUM(III) CATALYST
    TUNG, HS
    BRUBAKER, CH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 216 (01) : 129 - 137
  • [50] A readily prepared, highly reusable and active polymer-supported molybdenum carbonyl Schiff base complex as epoxidation catalyst
    Grivani, Gholamhossein
    Tangestaninejad, Shahram
    Halili, Akbar
    INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (08) : 914 - 917
12345