Voltammetric determination of catechol and hydroquinone at poly (murexide) modified glassy carbon electrode

被引:54
|
作者
Kumar, A. Anil [1 ]
Swamy, B. E. Kumara [2 ]
Rani, T. Shobha [1 ]
Ganesh, P. S. [2 ]
Raj, Y. Paul [1 ]
机构
[1] Dravidian Univ, Dept Chem, Kuppam 517425, Andhra Pradesh, India
[2] Kuvempu Univ, Dept PG Studies & Res Ind Chem, Shimoga 577451, Karnataka, India
关键词
Catechol (CC); Hydroquinone (HQ); Glassy carbon electrode (GCE); Electropolymerization; Cyclic voltammetry (CV); SIMULTANEOUS ELECTROCHEMICAL DETERMINATION; REDUCED GRAPHENE OXIDE; PASTE ELECTRODE; SIMULTANEOUS ELECTROANALYSIS; IONIC LIQUID; FILM; NANOTUBES; BEHAVIOR; SENSOR; POLYMERIZATION;
D O I
10.1016/j.msec.2018.12.055
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
The electrochemical study of Catechol (CC) was studied in presence of Hydroquinone (HQ) using poly(murexide) modified glassy carbon electrode (MGCE) by cyclic voltammetric study. The modified electrode exhibited good affirmative response towards the electro chemical oxidation of CC in presence of HQ in 0.2 M phosphate buffer solution at the physiological of pH 7.4. The influence of scan rate, concentration and pH parameters were examined with the cyclic voltammetric method. The modified electrode showed good selectivity and sensitivity with an advantage of interference study and free determination of selected analytes in this experiment. Finally a simple, sensitive and selective method was developed for the determination of dihydroxybenzene isomeric compounds.
引用
收藏
页码:746 / 752
页数:7
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