Synthesis of the novel β-aminophosphoryl compounds and their acid-base properties and membrane-transport abilities towards carboxylic acids

被引：6
|
作者：
Cherkasov, R. A. [1 ]
Garifzyanov, A. R. [1 ]
Kurnosova, N. V. [1 ]
Matveeva, E. V. [2 ]
Odinets, I. L. [2 ]
机构：
[1] Kazan Volga Reg Fed Univ, Kazan 420008, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
beta-aminophosphonates; beta-aminophosphine oxides; green chemistry; reactions in water; acid-base properties; membrane-transport properties; carboxylic acids; AZA-MICHAEL REACTION;
D O I：
10.1007/s11172-012-0024-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The highly efficient synthesis of beta-aminophosphoryl compounds with one and two ethylphosphoryl groups was performed by the addition of amines to the vinylphosphoryl compounds in water as a solvent. The acid-base properties and membrane-transport abilities of the target compounds towards carboxylic acids were studied. Selectivity towards acetic acid was revealed.
引用
收藏
页码：174 / 180
页数：7
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