Effect of SiO2/Al2O3 Ratio on Crystallization and Dielectric Properties of Barium Strontium Titanate Glass-Ceramics

被引:15
|
作者
Wang, X. [1 ]
Zhang, Y. [1 ]
Cui, L. [1 ]
Baturin, I. S. [2 ]
机构
[1] Tsinghua Univ, Beijing Fine Ceram Lab, State Key Lab New Ceram & Fine Proc, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
[2] Ural Fed Univ, Ferroelect Lab, Inst Nat Sci, Ekaterinburg 620000, Russia
基金
中国国家自然科学基金; 俄罗斯基础研究基金会;
关键词
Barium strontium titanate; network former; network modifier; dielectric properties; glass ceramics;
D O I
10.1080/00150193.2013.778182
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of (SiO2Al2O3)-Al-/ ratio on crystallization and dielectric properties of barium strontium titanate (BST) glass-ceramics has been investigated by differential scanning calorimetry (DSC), X-ray diffractometry (XRD), Raman spectrometry, and dielectric measurements. The experimental results showed that appropriate SiO2/Al2O3 ratio promoted the crystallization of a ferroelectric BST phase and improved the dielectric properties of the BST glass-ceramics. These studies revealed that the Al2O3 not only served as a network former, but also acted as a network modifier, weakening the network. Additionally, the variation of the SiO2/Al2O3 ratio significantly influenced the dielectric properties of the BST glass-ceramics.
引用
收藏
页码:109 / 114
页数:6
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