Functionalization of highly electrophilic N-(2,2,2-trichloroethylidene)- and N-(2,2-dichloro-2-phenylethylidene) arenesulfonamides with dithiooxamide

被引:3
|
作者
Rozentsveig, G. N. [1 ]
Fedotova, A. I. [1 ]
Serykh, V. Yu. [1 ]
Chernyshev, K. A. [1 ]
Rozentsveig, I. B. [1 ]
机构
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Div, Irkutsk 664033, Russia
关键词
SECONDARY-AMINES; DERIVATIVES; THIOAMIDES;
D O I
10.1134/S1070428012040021
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Depending on the reactant ratio, dithiooxamide (ethanedithioamide) reacted as N-nucleophile or N,N'-binucleophile with highly electrophilic aldimines, N-(2,2,2-trichloroethylidene)- and N-(2,2-dichloro-2-phenylethylidene)arenesulfonamides, to give the corresponding mono- or bis-adducts, N-[2-polychloro-1-(arylsulfonylamino) ethyl]ethanedithioamides or N,N'-bis[2-polychloro-1-(arylsulfonylamino)ethyl]ethanedithioamides, in good yield.
引用
收藏
页码:481 / 484
页数:4
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