Oxygen release from SrCo0.8Fe0.2O3-δ

被引:4
|
作者
Starkov, I. A. [1 ]
Bychkov, S. F. [1 ]
Matvienko, A. A. [1 ]
Nemudry, A. P. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochem, Novosibirsk 630128, Russia
关键词
PERMEATION; BA0.5SR0.5CO0.8FE0.2O3-DELTA; OXIDE;
D O I
10.1134/S0020168513080189
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have studied oxygen release from a membrane material with the composition SrCo0.8Fe0.2O3 - delta of various sizes in the temperature range 600-900A degrees C in a flow reactor at oxygen partial pressures from 0.2 to 10(-5) atm. The results demonstrate that the oxygen release from samples 50 mu m to 2 mm in size at temperatures above 800A degrees C can be described in terms of a quasi-equilibrium model. For fine powders, a parts per thousand currency sign63 mu m in size, the temperature range of quasi-equilibrium oxygen release begins at t a parts per thousand yen 600A degrees C.
引用
收藏
页码:916 / 922
页数:7
相关论文
共 50 条
  • [21] Phase stability and oxygen non-stoichiometry of SrCo0.8Fe0.2O3-δ measured by in situ neutron diffraction
    McIntosh, Steven
    Vente, Jaap F.
    Haije, Wim G.
    Blank, Dave H. A.
    Bouwmeester, Henny J. M.
    SOLID STATE IONICS, 2006, 177 (9-10) : 833 - 842
  • [22] Oxygen permeability, thermal expansion and stability of SrCo0.8Fe0.2O3-δ-SrAl2O4 Composites
    Yaremchenko, A. A.
    Kharton, V. V.
    Avdeev, M.
    Shaula, A. L.
    Marques, F. M. B.
    SOLID STATE IONICS, 2007, 178 (19-20) : 1205 - 1217
  • [23] Oxygen sorption/desorption kinetics of SrCo0.8Fe0.2O3-δ perovskite adsorbent for high temperature air separation
    Hao, Peixuan
    Shi, Yixiang
    Li, Shigang
    Liang, Shuguang
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2018, 24 (01): : 65 - 71
  • [24] Remarkable dependence of electrochemical performance of SrCo0.8Fe0.2O3-δ on A-site nonstoichiometry
    Liu, Huanying
    Zhu, Xuefeng
    Cong, You
    Zhang, Tianyu
    Yang, Weishen
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (20) : 7234 - 7239
  • [25] Effect of Zr4+ doping on the oxygen stoichiometry and phase stability of SrCo0.8Fe0.2O3-δ oxygen separation membrane
    Chen, W.
    Zuo, Y. B.
    Chen, C. S.
    Winnubst, A. J. A.
    SOLID STATE IONICS, 2010, 181 (21-22) : 971 - 975
  • [26] Oxygen production performance and structure of SrCo0.8Fe0.2O3-δ synthesized by combined EDTA-citrate complexing process
    Shen, Qiu-Wan
    Zheng, Ying
    Luo, Cong
    Zheng, Chu-Guang
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2015, 43 (07): : 890 - 896
  • [27] SrCo0.8Fe0.2O3-δ sorbent for high-temperature production of oxygen-enriched carbon dioxide stream
    Rui, Zebao
    Ding, Jingjing
    Li, Yongdan
    Lin, Y. S.
    FUEL, 2010, 89 (07) : 1429 - 1434
  • [28] SrCo0.8Fe0.2O3-δ的制备及稳定性能表征
    樊传刚
    黄显怀
    李栋才
    檀杰
    张国栋
    安徽工业大学学报(自然科学版), 2004, (03) : 196 - 198
  • [29] SrCo0.8Fe0.2O3-δ及SrCo0.8Fe0.1Sn0.1O3-δ的热学性能与透氧性能研究
    樊传刚
    刘卫
    左艳波
    邓增强
    黄祥贤
    陈初升
    无机材料学报, 2006, (05) : 1141 - 1146
  • [30] A novel Nb2O5-doped SrCo0.8Fe0.2O3-δ oxide with high permeability and stability for oxygen separation
    Zhang, Guangru
    Liu, Zhengkun
    Zhu, Na
    Jiang, Wei
    Dong, Xueliang
    Jin, Wanqin
    JOURNAL OF MEMBRANE SCIENCE, 2012, 405 : 300 - 309