Rhodium(III)-Catalyzed Intermolecular N-Chelator-Directed Aromatic C-H Amidation with Amides

被引：102
|
作者：
Zhao, Huaiqing [1 ]
Shang, Yaping [1 ]
Su, Weiping [1 ]
机构：
[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 19期
关键词：
CATALYZED DIRECT AMINATION; CARBON-NITROGEN BONDS; ARENES; ACTIVATION; RHODIUM; FUNCTIONALIZATION; RH; VERSATILE; ALKENES; ALKYNES;
D O I：
10.1021/ol4024776
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rh(III)-catalyzed intermolecular direct aromatic C-H bond amidation with amides has been accomplished under mild reaction conditions. This protocol is applicable to a broad range of N-chelator-containing arenes amidated with aromatic and aliphatic sulfonamides. A possible mechanism is proposed according to the experimental results.
引用
收藏
页码：5106 / 5109
页数：4
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