Synthesis of the first stable pentaco-ordinate 1,2-thiaphosphetene

被引：15

作者：

Kawashima, T ^{[1
]}

Iijima, T ^{[1
]}

Kikuchi, H ^{[1
]}

Okazaki, R ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 144卷

关键词：

pentacoordinate; 1; 2-thiaphosphetenes; Wittig reaction; the Martin ligand; thermolysis;

D O I：

10.1080/10426509908039519

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pentacoordinate 1,2-thiaphosphetenes bearing the Martin ligand were synthesized:by the reaction of the corresponding phosphorus ylide with isophiocyanates. Their mass and NMR spectral data showed that they have 1:2 adducts of the phosphorus ylide and isothiocyanates, which have a distorted trigonal bipyramid with oxygen and sulfur atoms at the apical positions. Thermolysis of the phenyl isothiocyanate adduct gave the corresponding cyclic thiophosphinate as a phosphorus-containing product in almost quantitative yield.

引用

页码：149 / 152

页数：4

共 50 条

[41] AMIDE CATALYZED FACILE ISOMERIZATION OF 5,6-DYHYDROISOQUINOLINES - SYNTHESIS OF STABLE 1,2-DIHYDROISOQUINOLINES
KASTURI, TR
KRISHNAN, L
TETRAHEDRON LETTERS, 1980, 21 (09) : 865 - 866
[42] THE SYNTHESIS AND CHEMI-LUMINESCENCE OF A STABLE 1,2-DIOXETHANE - AN ORGANIC-CHEMISTRY LABORATORY EXPERIMENT
MEIJER, EW
WYNBERG, H
JOURNAL OF CHEMICAL EDUCATION, 1982, 59 (12) : 1071 - 1072
[43] COMPLEXES WITH MACROCYCLIC LIGANDS .3. PENTACO-ORDINATE METAL-COMPLEXES WITH 1,4,7,10,12,12-HEXAMETHYL-1,4,7,10-TETRAAZACYCLOTRIDECANE, 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE AND 1,4,5,8,11,12-HEXAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE
BUXTORF, R
STEINMAN.W
KADEN, TA
CHIMIA, 1974, 28 (01) : 15 - 18
[44] First synthesis of pyrrolo[1,2:1′,2′]azepino[5,6-b]indole derivatives
Perron, J
Joseph, B
Mérour, JY
TETRAHEDRON LETTERS, 2003, 44 (35) : 6553 - 6556
[45] The first synthesis of the benzo[b]indolo[1,2-h][1,7]naphthyridine ring system
Baranova, Olga V.
Zhidkov, Maxim E.
Dubovitskii, Sergey V.
TETRAHEDRON LETTERS, 2011, 52 (18) : 2397 - 2398
[46] First stereospecific synthesis of (E)-1,2-bis(selenocyanato)ethenes by the addition of dicyanodiselenide to acetylenes
Potapov, V. A.
Amosova, S. V.
Dudareva, G. N.
Shestakova, V. Y.
Recueil des Travaux Chimiques des Pays-Bas, 1996, 115 (10):
[47] First Synthesis of Ferrocenyl-Substituted 1,2-Dihydro-2-oxopyridine-3-carbonitriles
Zhang, Hong
Li, Yang
Gao, Wentao
HELVETICA CHIMICA ACTA, 2013, 96 (11) : 2134 - 2140
[48] Synthesis, characterization, and reactivity of the first uranium metallocene 1,2-bis(diphenylphosphino)acetylene complexes
Pagano, Justin K.
Scott, Brian L.
Morris, David E.
Kiplinger, Jaqueline L.
INORGANICA CHIMICA ACTA, 2018, 482 : 347 - 352
[49] The first synthesis and characterisation of elusive cone 1,2-diformyl tetralkoxycalix[4]arenes and their derivatives
Sartori, A
Casnati, A
Mandolini, L
Sansone, F
Reinhoudt, DN
Ungaro, R
TETRAHEDRON, 2003, 59 (29) : 5539 - 5544
[50] First stereospecific synthesis of (E)-1,2-bis(selenocyanato)ethenes by the addition of dicyanodiselenide to acetylenes
Potapov, VA
Amosova, SV
Dudareva, GN
Shestakova, VY
Zhnikin, AR
Petrov, BV
Aksamentova, TN
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1996, 115 (10): : 443 - 443

← 1 2 3 4 5 →