Studies of copper(I) and silver(I) complexes with arylazoimidazoles

被引：0
|
作者：
Santra, PK [1 ]
Misra, TK [1 ]
Sinha, C [1 ]
机构：
[1] Univ Burdwan Golapbag, Dept Chem, Burdwan 713104, W Bengal, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 01期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N(1)-Alkyl-2-(dimethylphenylazo)imidazoles (L and L') yield bis-chelated complexes [ML2](ClO4) (M = Cu (2,3) and Ag (4,5)). The complexes are 1:1 electrolytes in MeOH and the composition is supported by Jobs method of continuous variation and molar ratio method. The structure of ligands and complexes are established by H-1 NMR spectral data and the signal pattern suggests that the chelate rings are magnetically equivalent (C-2-symmetry). The redox studies have also been carried out.
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页码：82 / 86
页数：5
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