Dynamics of copper electrodeposition onto fibrous carbon electrodes with electrical conductivity varying across their thickness

被引:0
|
作者
Varentsov, V. K. [1 ]
Yusin, S. I. [2 ]
机构
[1] Novosibirsk State Tech Univ, Novosibirsk, Russia
[2] Russian Acad Sci, Inst Solid State Chem & Mechanochem, Siberian Branch, Novosibirsk, Russia
关键词
Copper Deposit; Sulfuric Acid Solution; Front Side; Rear Side; Fourth Layer;
D O I
10.1134/S1070427212120129
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Distribution of copper in its electrodeposition from a sulfuric acid solution onto fibrous carbon electrodes with electrical conductivity varying across their thickness, the deposition rate of copper, and the current efficiency by copper were studied in relation to the electrolysis duration, electrical conductivity of the electrode, geometric current density, and solution flow rate. The main factors governing the distribution of copper across the electrode thickness and the electrolysis parameters beginning from the process onset till the "clogging" of a part of the electrode by the metal were determined.
引用
收藏
页码:1861 / 1870
页数:10
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