Palladium-Catalyzed Diarylmethyl C(sp3)-C(sp2) Bond Formation: A New Coupling Approach toward Triarylmethanes

被引：86
|
作者：
Xia, Ying [1 ,2 ]
Hu, Fangdong [3 ]
Liu, Zhenxing [1 ,2 ]
Qu, Peiyuan [1 ,2 ]
Ge, Rui [1 ,2 ]
Ma, Chen [3 ]
Zhang, Yan [1 ,2 ]
Wang, Jianbo [1 ,2 ]
机构：
[1] Peking Univ, BNLMS, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 07期
关键词：
ARYL HALIDES; MIGRATORY INSERTION; N-TOSYLHYDRAZONES; SUBSTITUTED OLEFINS; NOBEL LECTURE; ARYLATION; DERIVATIVES; REACTIVITY; COMPLEXES; CARBENE;
D O I：
10.1021/ol400690t
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed reductive coupling reactions between N-tosylhydrazones and aryl halides lead to the formation of C(sp(3))-C(sp(2)) bonds. This approach provides a general route for the synthesis of triarylmethanes.
引用
收藏
页码：1784 / 1787
页数：4
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