Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)2

被引：6

作者：

Huang, Hongwei ^{[1
]}

Yao, Wenjiao ^{[2
]}

He, Ying ^{[1
]}

Tian, Na ^{[1
]}

Chen, Chuangtian ^{[2
]}

Zhang, Yihe ^{[1
]}

机构：

[1] China Univ Geosci, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing 100083, Peoples R China

[2] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

来源：

MATERIALS RESEARCH BULLETIN | 2013年 / 48卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Optical materials; Crystal growth; X-ray diffraction; ANIONIC GROUP; NLO CRYSTALS; ALIGNMENT; POLAR; UNITS;

D O I：

10.1016/j.materresbull.2013.04.062

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Single crystal of the semiorganic NLO material NaB(L-C4H4O5)(2) has been grown with sizes up to 8 x 5 x 2 mm(3) by the slow evaporation method. The crystal structure of this compound was determined by single crystal X-ray diffraction. It crystallizes in the Monoclinic space group P2 with lattice parameters a = 5.4045(11) angstrom, b = 11.692(2) angstrom, c = 9.4773(19) angstrom and Z=2. Thermal analysis demonstrated NaB(L-C4H4O5)(2) are thermally stable up to 280 degrees C. NaB(L-C4H4O5)(2) exhibits an absorption edge about 220 nm in the UV region. The powder second-harmonic generation (SHG) measurement performed on the ground crystal indicates that it has a NLO efficiency of about 2 times that of KDP (KH2PO4) standard. In addition, the origin of stronger SHG effect was discussed. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：3077 / 3081

页数：5

共 50 条

[21] Growth and characterization of a novel UV nonlinear optical crystal:: [MnHg(SCN)4(H2O)2] • 2C4H9NO
Wang, XQ
Xu, D
Lü, MK
Yuan, DR
Huang, J
Cheng, XF
Xie, TX
Zhang, GH
Wang, SL
Guo, SY
Liu, JR
Yang, ZH
Wang, P
JOURNAL OF CRYSTAL GROWTH, 2002, 234 (2-3) : 469 - 479
[22] Studies on the synthesis, growth, crystal structure, and nonlinear optical properties of a novel nonlinear optical crystal: L-argininium-4-nitro phenolate monohydrate (LARP)
Srinivasan, P.
Vidyalakshmi, Y.
Gopalakrishnan, R.
CRYSTAL GROWTH & DESIGN, 2008, 8 (07) : 2329 - 2334
[23] Studies on the growth, structural, thermal, mechanical and optical properties of the semiorganic nonlinear optical crystal L-glutamic acid hydrobromide
Dhanasekaran, P.
Srinivasan, K.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2013, 74 (07) : 934 - 942
[24] Synthesis, Structure, and the Second-order Nonlinear Optical Properties of a Borate-carboxylic Acid Compound: KB[L-(-)-C4H4O5]2·H2O
杨坤
杨明
雍胜利
张骁勇
罗军华
ChineseJournalofStructuralChemistry, 2019, 38 (08) : 1398 - 1403
[25] Synthesis, Structure, and the Second-order Nonlinear Optical Properties of a Borate-carboxylic Acid Compound: KB[L-(-)-C4H4O5]2•H2O
Yang Kun
Yang Ming
Yong Sheng-Li
Zhang Xiao-Yong
Luo Jun-Hua
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (08) : 1398 - 1403
[26] Bulk Crystal Growth and Optical and Thermal Properties of the Nonlinear Optical Crystal L-Histidinium-4-nitrophenolate 4-Nitrophenol (LHPP)
Chen, Tianliang
Sun, Zhihua
Song, Cheng
Ge, Yan
Luo, Junhua
Lin, Wenxiong
Hong, Maochun
CRYSTAL GROWTH & DESIGN, 2012, 12 (05) : 2673 - 2678
[27] Synthesis, growth, structure and nonlinear optical properties of a semiorganic 2-carboxy pyridinium dihydrogen phosphate single crystal
Nagapandiselvi, P.
Baby, C.
Gopalakrishnan, R.
OPTICAL MATERIALS, 2015, 47 : 398 - 405
[28] Crystal structure and optical of novel (N(C2H5)4)[Nd(hfa)4(H2O)] tetrakis complex
Mech, Agnieszka
POLYHEDRON, 2008, 27 (01) : 393 - 405
[29] SrBeB2O5: Growth, crystal structure and optical properties
Yao, Wenjiao
Wang, Xiaoshan
Huang, Hongwei
Xu, Tao
Jiang, Xingxing
Wang, Xiaoyang
Lin, Zheshuai
Chen, Chuangtian
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 593 : 256 - 260
[30] Centrosymmetric crystal structure and third order nonlinear optical properties of [2(C10H20O5) NH4] [Cd (SCN)3]: CCTC single crystal for optical application
Ramkumar, S.
Malliga, P.
OPTICAL AND QUANTUM ELECTRONICS, 2023, 55 (12)

← 1 2 3 4 5 →