Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)2

被引：6
|
作者：
Huang, Hongwei [1 ]
Yao, Wenjiao [2 ]
He, Ying [1 ]
Tian, Na [1 ]
Chen, Chuangtian [2 ]
Zhang, Yihe [1 ]
机构：
[1] China Univ Geosci, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
来源：
MATERIALS RESEARCH BULLETIN | 2013年 / 48卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Optical materials; Crystal growth; X-ray diffraction; ANIONIC GROUP; NLO CRYSTALS; ALIGNMENT; POLAR; UNITS;
D O I：
10.1016/j.materresbull.2013.04.062
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Single crystal of the semiorganic NLO material NaB(L-C4H4O5)(2) has been grown with sizes up to 8 x 5 x 2 mm(3) by the slow evaporation method. The crystal structure of this compound was determined by single crystal X-ray diffraction. It crystallizes in the Monoclinic space group P2 with lattice parameters a = 5.4045(11) angstrom, b = 11.692(2) angstrom, c = 9.4773(19) angstrom and Z=2. Thermal analysis demonstrated NaB(L-C4H4O5)(2) are thermally stable up to 280 degrees C. NaB(L-C4H4O5)(2) exhibits an absorption edge about 220 nm in the UV region. The powder second-harmonic generation (SHG) measurement performed on the ground crystal indicates that it has a NLO efficiency of about 2 times that of KDP (KH2PO4) standard. In addition, the origin of stronger SHG effect was discussed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3077 / 3081
页数：5
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