Designing high-capacity cathode materials for sodium-ion batteries

被引：53
|
作者：
Jian, Zelang [1 ]
Yu, Haijun [1 ]
Zhou, Haoshen [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058568, Japan
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2013年 / 34卷
关键词：
High-capacity; Na-rich layered oxide; Sodium-ion batteries; Cathode; LOW-COST; PERFORMANCE; COMPOSITE;
D O I：
10.1016/j.elecom.2013.06.017
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Na-rich layered oxides as cathode materials for sodium-ion batteries were designed using an electrochemical method based on Li-rich layered oxides. The materials show high specific capacity that can reach 234 mAh/g at a current of 5 mA/g. The energy density of this material (644 Wh/kg) is even higher than those of commercial cathodes for lithium-ion batteries, such as LiFePO4 and LiMn2O4. Kinetic analysis of Na+ insertion/extraction into/from the Na-rich layered oxide reveals that the Na+ diffusion coefficient is about 10(-14) cm(2)/s. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：215 / 218
页数：4
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