Synthesis of two-dimensional molybdenum carbide, Mo2C, from the gallium based atomic laminate MO2Ga2C

被引：326

作者：

Meshkian, Rahele ^{[1
]}

Naslund, Lars-Ake ^{[1
]}

Halim, Joseph ^{[1
,2
]}

Lu, Jun ^{[1
]}

Barsoum, Michel W. ^{[1
,2
]}

Rosen, Johanna ^{[1
]}

机构：

[1] Linkoping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, SE-58183 Linkoping, Sweden

[2] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA

来源：

SCRIPTA MATERIALIA | 2015年 / 108卷

基金：

瑞典研究理事会; 欧洲研究理事会;

关键词：

2D materials; Layered structures; MXene; Transmission electron microscopy (TEM); Energy dispersive X-ray spectroscopy (EDS); HIGH VOLUMETRIC CAPACITANCE; LITHIUM-ION BATTERIES; TITANIUM CARBIDE; THERMOELECTRIC-MATERIALS; M(N+1)AX(N) PHASES; MXENE;

D O I：

10.1016/j.scriptamat.2015.07.003

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We report on the synthesis of a two-dimensional transition metal carbide, MO2C, (MXene) obtained by immersing Mo2Ga2C thin films in hydrofluoric acid. Experimental evidences for neither synthesis of a Mo-based MXene nor selective etching of Ga from an atomic nanolaminate have previously been presented. MXene formation is verified through X-ray diffraction, transmission electron microscopy, and energy dispersive X-ray spectroscopy. This discovery unlocks new potential applications for Mo-based MXenes in a host of applications, from thermoelectrics to catalysis and energy storage. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页码：147 / 150

页数：4

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